Project's information
Project's title | Fabrication of nanocomposite coatings, containing metal oxides to protect materials in tropical climate |
Project’s code | QTBY01.08/23-24 |
Research hosting institution | Institute for Tropical Technology |
Coordinating unit, co-chair | Francisk Skorina Gomel State University, Belarus |
Project leader’s name | Dr. Nguyen Tuan Anh and Assoc. Prof. Dr. Kovalenko Dmitry Leonidovich |
Project duration | 01/01/2023 - 31/12/2024 |
Project’s budget | 200 million VND |
Classify | Excellent |
Goal and objectives of the project | - Fabricate a protective coating based on acrylic-polyurethane resins and ZnO-Ag nanoparticles with good mechanical properties and high self-cleaning ability (ACPU nanocomposite coating) |
Main results | - For ACPU nanocomposite coating, SEM/TEM analysis revealed that nano-ZnO and nano-Ag particles were hybridized, with nano-Ag particles (10-30 nm in size) attached to the surface of rod-shaped nano-ZnO particles (width: 30-70 nm, length: 100-200 nm). These ZnO-Ag was well dispersed in the polymer coating matrix at a content of ≤ 2%. When the content of ZnO-Ag was > 2%, agglomeration of ZnO-Ag particles was observed, reducing the mechanical properties of the coating. Mechanical tests showed that when the content of ZnO-Ag was ≤ 2%, the adhesion and relative hardness of the coatings did not change compared to the ACPU coating without nanoparticles. However, the presence of hybrid nanoparticles in coating matrix enhanced the mechanical properties, increasing with the nanoparticle content. When the content of ZnO-Ag increased from 0 to 2% by weight, both the impact strength and abrasion resistance increased proportionally with the ZnO-Ag content, increasing from 174 kg.cm and 132.7 L/mil to 187 kg.cm and 154.6 L/mil, respectively. Data on the reflectance coefficient for the SHR heat-resistant coating system with the artificial contamination showed that after UV irradiation, the topcoat recovered its reflectance coefficient more strongly, reflecting the self-cleaning ability of the ACPU/ZnO-Ag coating. |
Novelty and actuality and scientific meaningfulness of the results | A topcoat was successfully fabricated using a solvent-based dispersion of acrylic polyurethane resin and ZnO-Ag hybrid nanoparticles. The resulting polymer nanocomposite coating (ACPU/ZnO-Ag) exhibited good mechanical properties and self-cleaning capability via a photocatalytic mechanism. |
Products of the project | - Kovalenko, D.L., Uong Van, V., Mac, V.P., Nguyen, T.V., Pham Thi, L., Nguyen*, T.A., Gaishun, V.E., Vaskevich, V.V. and Tran, D.L. (2024), "Effect of graphene on mechanical and anti-corrosion properties of TiO2-SiO2 sol-gel coating", Anti-Corrosion Methods and Materials, Vol. 71 No. 6, pp. 820-830. https://doi.org/10.1108/ACMM-05-2024-3023 |
Recommendations | The two-coat paint system, based on the sol-gel primer and the polymer nanocomposite topcoat, holds great promise for applications as a corrosion-resistant and self-cleaning coating in the automotive, motorcycle, aerospace, and space industries. |
Images of project | ![]() |