| Main results | - Theoretical results: • The project has successfully synthesized flame-retardant substances such as TiO2, Mg(OH)2, bentonite, APP, and nano-silica. These materials are cost-effective, with simple production methods that can be scaled up to pilot production. • The project has systematically studied SAP materials derived from natural sources such as cellulose, alginate, and starch and has developed specific formulations for gels formed from these SAPs as follows: • SAPNB has been synthesized by graft polymerization of acrylic acid and the crosslinker N, N'-methylene-bisacrylamide (MBA) combined with nano silica, nano bentonite, and nano Mg(OH)2. This material produces a gel formulation with excellent adhesion to material surfaces, impeding combustion. The SAPHP01 additive, with 30% SAPNB content, possesses a high hydrophilic-lipophilic balance (HLB=10), allowing rapid water absorption to form gel01 (comprising 5% SAPHP01 and 95% water), which is used as a material to prevent and extinguish fires. Experimental results indicate that gel01 can effectively extinguish Class I fires in under 300s , with fire resistance ranging from 1000 to 1300°C for 40s when applied in a 2 mm layer. • The TS-AA-AMPS/APP material was synthesized from modified starch, AA, and AMPS, incorporating 3% APP by weight. The SAPHP02 additive, used to formulate gel02 containing 32% TS-AA-AMPS/APP, has an HLB value of 4.3, offering excellent water absorption and retention. Gel02, prepared from 3.5% SAPHP02 and 96.5% water, demonstrates exceptional adhesion to wooden surfaces (99%). Testing of the gel02 system shows a Class I fire extinguishment time of less than 300 seconds (262 seconds) and fire resistance of up to 45 seconds with a 2 mm gel coating. • The fire-extinguishing gel can be supplied in either powder or viscous gel form and is easily deployable using standard firefighting equipment. The VH-GEL01 and VH-GEL02 systems have undergone systematic testing, from laboratory research to field trials at authorized firefighting agencies. These gels have proven effective in preventing and suppressing fires on wood, tarpaulins, and straw. Based on field experiments, the project developed and issued a technical specification (TCCS) for VH-GEL01 for fire prevention and suppression, serving as a foundation for establishing a national standard (TCVN) and enabling future research comparisons. • The gels produced by this project are cost-effective, environmentally friendly, and utilize safe production methods, with scalability to large-scale manufacturing. • The project enhances the scientific and technological capabilities of participating organizations, especially in the field of firefighting materials. It also contributes to research and development of new products using locally available, eco-friendly materials in Vietnam for fire prevention and national security purposes. - Applied results: • New products have been developed with effective fire extinguishing capabilities that meet Vietnamese standards and are of comparable quality to international products, eliminating the need for imports and ensuring human and social safety. The resulting products are more cost-effective than imports and can be researched and produced domestically. • The products are technically optimized, competitively priced (approximately 150,000 VND/liter), safe to produce, easily scalable, and completely non-toxic. They represent an economical and environmentally friendly solution with the potential to compete with international brands. This breakthrough lays the foundation for establishing TCVN standards in firefighting and opens up broader application and research opportunities in the future. |
| Products of the project | - Scientific papers in referred journals (list): • Two articles published in international journals indexed in SCIE. Giang H. Le, Duong A. Thanh, Pham T.H. My, Trang T.T. Pham, Trang T.T. Quan, Tung N. Nguyen, Quang K. Nguyen, Quoc Anh Ngo, "One-step synthesis of super-absorbent nanocomposite hydrogel based on bentonite," Materials Research Express, 10(1), (2023), 015001, SCIE IF >2, Q2. Ngoc Binh Vo, Thi Yen Tran, Le Thanh Hang Nguyen, Thanh Tung Nguyen, Van Tuyen Nguyen, and Quoc Anh Ngo, "Synthesis, characterization, and swelling properties of a novel tapioca-g-Poly(Acrylic acid−2−acrylamido−2−methylpropane sulfonic acid)/ammonium polyphosphate superabsorbent polymer," Materials Research Express, 11, (2024), 025302, SCIE IF >2, Q2. • One article published in a Scopus-indexed journal. Giang H. Le, Duong A. Thanh, Pham T.H. My, Trang T.T. Pham, Trang T.T. Quan, Quan Minh Nguyen, Quoc Anh Ngo, "Synthesis of magnesium hydroxide powder and dry powders for application in extinguishing petroleum fires," Vietnam Journal of Chemistry, 62(S1), (2024), 68-75, Scopus, Q3. • One article published in a national journal. Le Ha Giang, Duong Anh Thanh, Pham Thi Ha My, Pham Thi Thu Trang, Quan Thi Thu Trang, Nguyen Ha Thanh, Pham The Chinh, Nguyen Van Chien, Ngo Quoc Anh, "Synthesis of thermally sensitive composite gel containing nanocomposite hydrogel for extinguishing Class A fires," TNU Journal of Science and Technology, 228(10), (2023), 296-303. • All articles are available online, including the project code in the acknowledgement section. - Patents (list): • Utility Solution: The process for producing gel materials to prevent and extinguish fires, and the gel materials obtained from this method, has been accepted as a valid application according to decision number 39587/QĐ-SHTT.IP dated June 7, 2023. - Technological products (describe in details: technical characteristics, place): • 10 kg of SAPNB was produced for preparing VH-GEL01 fire-extinguishing gel and testing purposes, with 2 kg remaining. • 10 kg of TS-AA-AMPS/APP was produced for preparing VH-GEL02 fire-extinguishing gel and testing purposes, with 2 kg remaining. • 200 liters of water-based fire-extinguishing gel, labeled as VH-GEL01. • 200 liters of water-based fire-extinguishing gel, labeled as VH-GEL02. • 100 liters of SAPHP01 suspension for preparing VH-GEL01, labeled as VH-SAPHP01, containing an SAPNB equivalent of 30 kg. • 70 liters of SAPHP02 suspension for preparing VH-GEL02, labeled as VH-SAPHP02, containing TS-AA-AMPS/APP equivalent to 22.4 kg.All products are stored in sealed containers and kept at the Institute of Chemistry. - Other products (if applicable): • The project successfully trained one Master's degree graduate in Analytical Chemistry, awarded the degree with certificate number THS.00665 in Thai Nguyen on September 11, 2023. • The project developed one technical standard for fire-extinguishing gel products. • The project successfully established a pilot-scale production process for two fire-extinguishing gels. • The project successfully developed a pilot-scale preparation process for two fire-extinguishing gel formulations. |