| Main results |
Two catalysts of optimum composition (10%CuO/γ-Al2O3 and 10%CuO+20%CeO2/γ-Al2O3) have been obtained. The physico - chemical properties of the catalysts was studied by XRD, SEM, TEM, TPR, H2 chemical adsorbsion and BET adsorption methods. The kinetics of the reaction has been investigated in a flow-circulation sealed glass system; data on the mechanism of the process were obtained with the use of an unsteady state method and FT-IR. In the research results the highly-active catalysts have been obtained and kinetics of reaction deep oxidation of CO, p-xylene and mixtures has been established. The mechanism of deep oxidation of CO has been proposed. Research results are presented in 01 paper in the international journal, 01 paper in the Vietnamese journal, 01 paper in the proceeding of international Conference, 02 reports in the international and national conferences, 01 master and 01 graduated student also have been trained. |
| Novelty and actuality and scientific meaningfulness of the results |
- Exchange the experts and young researchers working in Russia and in Vietnam;
- Improve the research level of young researchers (2 Master, 1 graduate student);
- Support the implementation of Ph.D theses (Nguyen Tri);
- Improving the quality of research to reach the international level;
- Research results are presented in 01 ISI paper, 01 paper in the proceeding of international Conference, 01 paper in national journal, 02 reports in the international and national conferences, 01 master and 01 graduated student also have been trained;
- Production of the catalysts, which can be applied in treatment of industrial waste gas, waste gas from boilers and incinerators, contributing to reducing environmental pollution in Vietnam;
- Establishing the reaction kinetic model to serve for the design of the reactor.
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| Products of the project |
- Scientific papers in referred journals (list):
- Luu Cam Loc, Nguyen Tri, Yu. A. Agafonov, N.A. Gaidai, Hoang Tien Cuong, Ha Cam Anh, Ho Si Thoang, A.L. Lapidus and Huynh Ky Phuong Ha, Influence of Pt on the properties and activity of CuO-based catalysts for low temperature oxidation of carbon monoxide, Asean Engineering Journal, 2014 (Đã chấp nhận đăng)
- Luu Cam Loc, Nguyen Tri, Hoang Tien Cuong, Yu.A.Agafonov, N.A.Gaidai, Ho Si Thoang, A.L. Lapidus, Kinetics of Carbon Monoxide Oxidation over Modified Supported CuO Catalysts, Preprints of the Conference “New Technologies and Alternative Feedstocks in Petrochemistry and Refining” October 9-10. 2013. Dresden, Germany. PP. 199-205. (DGMK Tagungsbericht. 2013-2.)
- Nguyen Tri, Luu Cam Loc, Hoang Tien Cuong, Ha Cam Anh, Trinh Thi Yen Thi, Nguyen Thi Loan Phuong, Yu. A. Agafonov, N. A. Gaidai, Oxidation of CO over Pt-promoted CuO-catalyst in presence of steam and SO2, Journal Development of Science and Technology, 2014 (accepted)
- Luu Cam Loc, Nguyen Tri, Agafonov Yu. A., Gaidai N.A., Bui Thanh Huong, Lapidus A.L. Influence of Pt Additive on Catalytic Properties of Metallic Oxide Catalysts, 7th World Congress on Oxidation Catalysis, Saint Louis, Missouri, June 8-12th, 2013
- Nguyen Tri, Luu Cam Loc, Hoang Tien Cuong, Ha Cam Anh, Trinh Thi Yen Thi, Nguyen Thi Loan Phuong, Yu. A. Agafonov, N. A. Gaidai, Oxidation of CO over Pt-promoted CuO-catalyst in presence of steam and SO2, 9th Workshop of Ho Chi Minh City University of Science, 11/2014.
- Technological products (describe in details: technical characteristics, place):
- Two catalysts of high efficiency, used for total oxidation of mixture of CO and VOC, have been obtained.
- 3 kinetic equations of total oxidation of CO, p-xylene and their and mechanism of CO oxidation has been established, to serve for the design of reactors for industrial air treatment.
- Other products (if applicable): 01 master and 01 graduated student also have been trained.
- Nguyen Thi Loan Phuong, Investigation of kinetics of total oxidation of CO and p-xylene on Pt + CuO/γ-Al2O3 catalyst and the influence of steam and SO2 to the activity of the catalyst, Master Thesis, Can Tho University, 6/2014
- Duong Tien Nhac, Investigation of kinetics of total oxidation of CO and mixture of CO and p-xylene on 10%CuO/γ-Al2O3 catalyst, Graduate thesis, Ho Chi Minh City University of Technology.
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